Epsom salt is made of magnesium, sulfur, and oxygen bound as magnesium sulfate heptahydrate (MgSO4·7H2O).
For the full breakdown, see our best Epsom Salt guide.
Despite the name, Epsom salt has nothing in common with table salt. Table salt is sodium chloride; Epsom salt is a naturally occurring mineral compound of magnesium, sulfur, and oxygen. The “salt” label sticks because the crystal structure looks similar, but the chemistry is entirely different.
The name comes from Epsom, England, where the bitter mineral spring water first yielded these crystals. The compound is also called magnesium sulfate heptahydrate or its mineral name, epsomite. If you’re wondering what Epsom salt is made of at the molecular level, the answer is one magnesium atom, one sulfur atom, four oxygen atoms, and seven water molecules locked into each crystal.
Chemical Composition: Magnesium Sulfate Heptahydrate
The standard household product is the heptahydrate form, meaning each molecule carries seven water molecules in its crystal structure. The chemical formula is MgSO4·7H2O. That water of crystallization is part of the crystal itself, not moisture on the surface. When Epsom salt dissolves in a warm bath, those bonds break and release the magnesium and sulfate ions.
Magnesium makes up roughly 10% of the compound’s weight.
Anhydrous magnesium sulfate without the water molecules exists, but it’s a laboratory reagent, not the product sold in garden centers and drugstores. The heptahydrate is what you’ll find in every bag and carton.
Nutrient Role for Plants and Soil
Gardeners value Epsom salt for two elements: magnesium and sulfur. Both are secondary nutrients that plants need in meaningful amounts, though less than the primary nitrogen-phosphorus-potassium trio.
Magnesium sits at the center of every chlorophyll molecule, which is why a deficiency shows up as yellowing between the leaf veins. Sulfur supports protein formation and enzyme function. When soil tests show a genuine shortage of either element, dissolved Epsom salt delivers both at once.
Most soils don’t need it, though. Routine application without a soil test can push magnesium levels too high, which interferes with calcium uptake. The smart approach is testing first; if the test confirms a magnesium or sulfur gap, Epsom salt is an effective remedy.
Epsom Salt vs. Regular Salt: What’s the Difference?
| Property | Epsom Salt | Table Salt |
|---|---|---|
| Chemical name | Magnesium sulfate heptahydrate | Sodium chloride |
| Formula | MgSO4·7H2O | NaCl |
| Key elements | Magnesium, sulfur, oxygen | Sodium, chlorine |
| Taste | Bitter, unpalatable | Salty |
| Garden use | Magnesium/sulfur supplement | Weed killer only at high rates |
| Effect on soil | Adds nutrients, lowers pH slightly | Accumulates sodium, damages structure |
| CAS number | 10034-99-8 | 7647-14-5 |
Is It the Same as What You Buy at the Drugstore?
The Epsom salt sold for soaking sore muscles is chemically identical to the product marketed for gardening. Both are magnesium sulfate heptahydrate. The difference is labeling, packaging, and purity standards for human consumption.
FAQs
Does Epsom salt go bad or lose potency?
Epsom salt is a stable mineral compound that doesn’t spoil. It can absorb moisture from humid air and clump, but the chemical composition stays intact. Storing it in a sealed container in a dry spot keeps it free-flowing indefinitely, and it remains effective for soaking or soil application.
How much magnesium does Epsom salt add to soil?
A pound of Epsom salt delivers slightly under 10% magnesium by weight, which is about 45 grams of elemental magnesium. The actual amount available to plants depends on soil pH and organic matter. A soil test is the only reliable way to know how much your garden needs.
Can you eat Epsom salt?
References & Sources
- DailyMed, National Institutes of Health. “Epsom Salt Drug Label Information.” Official FDA drug facts label citing active ingredient and dosage directions.
- Wikipedia. “Magnesium Sulfate.” Background on the compound’s formula, history, and mineral name.
- PubChem, National Institutes of Health. “Epsom Salt Compound Summary.” CAS number and molecular structure data.
